Indian Journal of Chemistry


Sect. B: Organic Chemistry including Medicinal Chemistry;

Total visitors: 8753 since 08-02-2012



VOL. 51B


February 2012











Enantiospecific synthesis of pacifigorgianes

Enantiospecific synthesis of pacifigorgiane sesquiter­penes has been accomplished, employing entropy assisted RCM reaction.









A Srikrishna* & Dattatraya H Dethe


Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India












Trifluoroacetic acid catalyzed tetrahydro­pyranyla­tion of alcohols and phenols and direct conversion of THP ethers into acetates


An expedite and convenient procedure for tetrahydro­pyranylation of alcohols and phenols in dichloromethane and their depyranylation in methanol in the presence of trifluoroacetic acid at ambient temperature is developed. The reaction conditions are tolerable for a variety of functionalities. The direct conversion of tetrahydro­pyranyl ethers into their corresponding acetates under trifluoroacetic acid catalysis is also achieved.






R = alkyl / aryl







Naganjaneyulu Bodipati, Srinivasa Rao Palla & Rama Krishna Peddinti*


Department of Chemistry, Indian Institute of Technology, Roorkee 247 667, India




















Microwave-enhanced triton B catalyzed Suzuki coupling reaction








H M Meshram*, B R V Prasad, D A Kumar & B Ch K Reddy


Discovery Laboratory, Organic Chemistry Division – I, Indian Institute of Chemical Technology,

Hyderabad 500 007, India















Synthesis and identification of the novel urazole­diamine with phthalimide group


A diamine, 4-(4-phthalimidophenyl)-1,2,4-triazolidyne-3,5-diamine or urazolediamine has been synthesized in 8 steps from 4-nitrobenzoic acid. It can be used as a monomer for the preparation of polyesters, polyamides and polyimides.






H Mighani*, H Nasr Isfahani & S Mighani


Department of Chemistry, Golestan University, Gorgan, P.O.Box 155, Iran












Facile synthesis of steroidal complex having three heterocyclic moieties


Synthesis of 3-spiro-[3′′′-(2′′′-phenyl-4′′′oxo-1′′′,3′′′-thia­zolidin-5′′-yl)-1′′,3′′,4′′-thiadiazolo-(3′,4′-b)-thiazo­lin]-cholest-5-ene 4 form steroidal thiosemicarbazone is reported.








Shamsuzzaman*, Tabassum Siddiqui & Mohd Gulfam Alam


Department of Chemistry, Faculty of Science, Aligarh Muslim University, Aligarh 202 002, India




















A short and faster entrée to N-oxides: Transition metal acetylacetonates promoted aerobic oxidative transformation of tertiary nitrogen compounds to N-oxides


A conveniently fast method for the production of N-oxides from tertiary amines using aerobic oxidation and transition metal catalyst.







Rajendra Dongre*, Javed Sheikh, Dinesh Ghugal, Parvez Ali, Jyotsana Meshram & D S Ramteke


P G T D of Chemistry, R T M Nagpur University, Nagpur 440 033, India












Synthesis antimicrobial and antioxidant activities of some new 3-indolyl pyra­zolo[2,3-c]pyran and its derivatives


N1-isonicotinyl-1,4-dihydropyrano[2,3-c]pyrazoles (5a-e and 6a-e) have been synthesized. These compounds have been screened for their antimicrobial and antioxidant activities.









Saundane Anand R* & Yarlakatti Manjunatha


Department of Post-Graduate Studies and Research in Chemistry, Gulbarga University, Gulbarga 585 106, India












Synthesis, characterization and biological evaluation of allyl, benzyl and 4-nitrobenzyl derivatives of aminopyridinium bromides


A new series of allyl, benzyl and 4-nitrobenzyl derivatives of aminopyridiniumbromides have been synthesized. The antimicrobial activity of these compounds have been evaluated against S. aureus, P. murabilis, E. coli, C. albicans and A. niger by disc diffusion method.







C Muthukumar*, M Nallu, T Arunachalam, M Subramanian & C Balamurugan


PG and Research Department of Chemistry, J J College of Arts and Science, Pudukkottai 622 422, India




















Decipic acid and 12-acetyl apetalic acid from Calo­phyl­lum decipiens. Wight


Two new chromanones along with six known  compounds are reported for the first time from Calophyllum decipiens using 2D NMR techniques. Radical scavenging and antimycobacterial activities are studied.







M D Ajithabai*, B Rameshkumar, G Jayakumar, LuxmiVarma, Mangalam S Nair, Ajaikumar &
Gayathri P Nair


Department of Chemistry, Mahatma Gandhi College, Thiruvananthapuram 695 004, Kerala, India












Synthesis of 6-aryl-9-(4-hydroxy-3-ethoxyphenyl)-1,2,4-triazolo [4,3-a][1,8]naphthyridines under micro­wave irradiation


A simple and efficient method for the synthesis of 6-aryl-9-(4-hydroxy-3-ethoxyphenyl)-1,2,4-triazolo[4,3-a][1,8] naphthyridines 4 by the oxidation of the corresponding ethylvanillin 3-aryl-1,8-naphthyridin-2-ylhydrazones 3 using silicagel supported ferric chloride (SiO2-FeCl3) in solvent-free conditions under microwave irradiation has been described.







K Mogilaiah*, K Jagadeeshwar & A Nageswara Rao


Department of Chemistry, Kakatiya University, Warangal 506 009, India








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